i am not sure how far out Greenford is, but I used to jog from the Sainsbury's on Ladbrook Grove for a few miles west on the canal.
Now, I often bicycle to Paddington from the Sainsbury's on the canal - by the two humped bridges - and I occasionally go west for an extra 15 minutes of riding as a sort of work-out.
Compared to the Grand Union around Islington, it seems quite innocent. I have never had a bad experience nor have I felt concerned. But I am a reasonably fit guy. I would be a bit more cautious about recommending the route to a woman riding alone. Why not try to find someone to ride with?
Having said that, there do seem to be a reasonable number of bicyclists commuting on that route.
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